this ones pretty cool from a hackers viewpoint
http://www.damninteresting.com/?p=173
1982 ? Soviet gas pipeline. Operatives working for the Central Intelligence Agency allegedly (.pdf) plant a bug in a Canadian computer system purchased to control the trans-Siberian gas pipeline. The Soviets had obtained the system as part of a wide-ranging effort to covertly purchase or steal sensitive U.S. technology. The CIA reportedly found out about the program and decided to make it backfire with equipment that would pass Soviet inspection and then fail once in operation. The resulting event is reportedly the largest non-nuclear explosion in the planet's history.